Last modified: 2018-10-13
Abstract
Red Rice (Oryza sativa L.) Bran is a waste that is often found in our environment. Pigment rice contains polar pigmen anthocyanin. Anthocyanin is natural pigment that have low color stability and are easily degraded by environmental influences. In the present study, we have tried to increasing the color stability of antocyanins by copigmentation. Anthocyanin extraction was carried out using maceration techniques in ethanol solvents. The extract of antocyanin was characterizied by spectrophotometer UV-Vis and fourier transform infra red (FTIR). The results show that the spectrum UV-Vis and IR were obtained a chracteristics peak at 470, 420, 340 nm and hydroxyl group at 3400-3500 cm-1, respectively. The various of Fe3+ and Al3+ as copigment and compotition of anthocyanin to Fe3+ and Al3+ have been investigated. Anthocyanin stability was followed by measuring the loss of color by spectrophotometer UV-Vis, and the reluts show that Addition of Fe3+ and Al3+ could improve the anthocyanin stability.
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References
Boulton R. .2001. The Copigmentation of Anthocyanins and Its Role In The Color Of Red Wine: A Critical Review. American Journal of Enology and Viticulture,52(2):67-8.
Fahyuan, H.D., Samsidar, Farid, F., Heriyanti, Napitupulu, S., Pakpahan, S. 2015. Disain Prototipe Sel Surya DSSC (Dye Sensitized Solar Cell) Lapisan Grafit/TiO2 Berbasis Dye Alami. JoP. 1(1):5-11.
Fitria, A., Amun A., Ahmad F. 2016. Pembuatan Prototip Dye Sensitized Solar Cell (DSSC) Menggunakan Dye Ekstrak Buah Senduduk (Melastoma Malabathricum L) dengan Variasi Fraksi Pelarut dan Lama Perendaman Coating TiO2. Jurnal Fakultas Teknik. Vol. 3 : 1.
Goto, T., Hoshino, T. and Obha, M. 1976. Stabilization Effect of Neutral Salts on Anthocyanins: Flavilium Salts, Anhidrobase and Genuine Anthocyanins.J. Agr. Biol. Chem, 40(8): 1593-1596.
Hardeli., Anisa., Amun, A., Ahmad, F. 2013. Dye Sensitized Solar Cells (DSSC) Berbasis Nanopori TiO2 Menggunakan Antosianin dari Berbagai Sumber Alami. Prosiding Semirata FMIPA Universitas Lampung.
Hoshino, T., Matsumoto, U. and Goto, T., 1981.Journal Phytochemistry, 20:1971-1976.
Kementrian Perindustrian. 2014. Ketahanan Energi Indonesia Merosot. Kemenperin.go.id. Diakses pada tanggal 12 September 2017.
Misbachudin, M.C., Ferdy, S.R., Adita, S. 2014. Pengaruh pH Larutan Antosianin Strawberry dalam Prototipe Dye Sensitized Solar Cell (DSSC). Jurnal Fisika dan Aplikasinya, 10(2).
Munawaroh, H., Fadillah, G., Saputri, L.N.M.Z., Hanif, Q.A., Hidayat, R., Wahyuningsih, S. 2016. The Co-Pigmentation of Anthocyanin Isolated From Mangosteen Pericarp (Garcinia Mangostana L.) as Natural Dye For Dye Sensitized Solar Cell (DSSC). IOP Conf. Ser.: Mater. Sci. Eng. 107 012061.
Pangesti, S.A. 2015. Karakterisasi Pigmen Bunga Mawar (Lokal Batu) Dengan Kopigmentasi Katekin Ekstrak Teh Hitam Dan Teh Hijau. Doctoral Dissertation, Universitas of Muhammadiyan Malang.
Permana, R.A. and Putri, W.D.R., 2014. Pengaruh Proporsi Jagung dan Kacang Merah Serta Substitusi Bekatul Terhadap Karakteristik Fisik Kimia Flakes. Jurnal Pangan dan Agroindustri, 3(2).
Prasada, A.B., Fadli, U.M. and Supriyanto, A., 2016, November. Dye Oriza sativa glutinosa doped Fe as a active element of Dye Sensitized Solar Cell (DSSC). Journal of Physics: Conference Series, 776(1): 012008
Rattanachitthawat, S., Suwannalert P, Riengrojpitak S, Chaiyasut C, Pantuwatana S. 2010. Phenolic Content and Antioxidant Activities in Red Unpolished Thai Rice Prevents Oxidative Stress in Rats. J. Med Plants Res, 4: 796-801.
Rein, M. 2005.Copigmentation Reaction and Color Stability of Berry Anthocyanins. [Disertasi].Finland : Faculty of Agriculture and Forestry, University of Helsinki.
Simon, M., Aswani, Y., Peng, G., Robin, H.B., Basile, F.E.C., Negar, A.A., Ivano,T., Ursula, R., Nazeeruddin, K., Gratzel, M. 2014. Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers. Nature Chemistry,1861: 1-7.
Wadarta, I.W.R., dan I Wayan, A. 2014. Stabilitas Aktivitas Antioksidan Ekstrak Bekatul Beras Merah Terhadap Oksidator dan Pemanasan pada Berbagai pH. J.Teknol. dan Industri Pangan, 25(2): 193 – 199.
Wang, L.S. dan Stoner, G.D. 2008.Anthocyanins and Their Roles in Cancer Prevention.Cancer Letters, 269: 281- 290.
Wulandari, L., 2014. Isolasi Senyawa Antosianin Dari Bunga Mawar Merah (Rosa Hybrida Hort) Sebagai Sensitizer Pada Dye Sensitized Solar Cell (Dssc), Thesis Report, Universitas Sebelas Maret.